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In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.

In the HCCI Engine, inhomogeneity in fuel distribution and temperature in the pre-mixture exists microscopically, and has the possibility of affecting the ignition and combustion process. In this study, the effect of charge inhomogeneity in fuel distribution on the HCCI combustion process was investigated. Two-dimensional images of the chemiluminescence were captured by using a framing camera with an optically accessible engine in order to understand the spatial distribution of the combustion. DME was used as a test fuel. By changing a device for mixing air and fuel in the intake manifold, inhomogeneity in fuel distribution in the pre-mixture was varied. The result shows that luminescence is observed in a very short time in a large part of the combustion chamber under the homogeneous condition, while luminescence appears locally with considerable time differences under the inhomogeneous condition.

The purpose of this research is to get fundamental knowledge and to experimentally understand about combustion characteristics of the fuel mixture. This paper shows the Homogeneous Charge Compression Ignition (HCCI) characteristics of a mixture of n-Heptane and iso-Octane in a rapid compression machine. The experimental matrixes cover the n-Heptane mixing ratios, rn-Heptane, ranging from 0 to 100vol% and the equivalence ratios ranging from 0.1 to 0.6. The experimental study on the effect of mixing fuels focuses on the low temperature oxidation reaction temperatures, TL, the high temperature oxidation reaction temperatures, TH, the low temperature oxidation reaction starting times, tL, the high temperature oxidation reaction starting times, tH, and the degeneration period. The results show that as rn-Heptane decreases, tL and tH become longer and TL and TH increase by 30K. As the equivalence ratio increases, tL becomes longer but tH is not a function of equivalence ratio.

The exhaust gas composition was analyzed by gas chromatography, and combustion completion was investigated in a 2-stroke Homogeneous Charge Compression Ignition (HCCI) engine. The experiment was performed using n-Butane as a typical pure fuel to easily identify the origin of exhaust gas components. The effect of maximum gas temperature on combustion completion was investigated by both the experiment and the calculation. From the measurements of unburned n-Butane emission, the thickness of the quenching layer was estimated.

The operating range is restricted by knocking and misfiring in a homogeneous charge compression ignition (HCCI) engine. In an HCCI engine, the autoignition does not always mean the high combustion efficiency because the operating range to achieve high combustion efficiency is very narrowly restricted by knocking and high THC, CO emissions. In this study, we have investigated the operating conditions to achieve high combustion efficiency and low CO emission in a four-stroke HCCI engine using experimental analysis and elementary reactions calculation. It is shown that the combustion efficiency reaches higher than 90%, and the CO emission can be reduced considerably when the in-cylinder maximum gas temperature is over 1600K.

The characteristics of auto-ignition of DME/Air mixture in Homogeneous Charge Compression Ignition (HCCI) engine were investigated by numerical calculation with elementary reactions and experiment. Calculations were carried out using Di-Methyl Ether (DME) elementary reactions at 0 dimension and adiabatic condition. DME is paid attention as the alternative fuel of next generation because of its possibility to take the place of conventional fossil fuels. DME has good characteristics of auto-ignition and combustion with low flame temperature, and makes no soot because of its molecular structure. In autoignition process, DME shows two-stage combustion, heat release with low temperature reaction (LTR) and high temperature reaction (HTR). This characteristic is similar to higher hydrocarbons such as gasoline in auto-ignition process. In this study, analysis of HCCI combustion of DME/Air mixture was carried out by using numerical calculation and comparing with experimental results.

The combustion mechanism of the homogeneous charge compression ignition (HCCI) engine has been investigated by numerical calculations. Calculations were carried out using n-butane/air elementary reactions at 0 dimension and adiabatic condition to simplify the understanding of chemical reaction mechanisms in the HCCI engine without complexities of walls, crevices, and mixture inhomogeneities. n-Butane is the fuel with the smallest carbon number in the alkane family that shows two-stage auto-ignition, heat release with low temperature reaction (LTR) and high temperature reaction (HTR), similar to higher hydrocarbons such as gasoline at HCCI combustion. The CHEMKIN II code, SENKIN and kojima's n-butane elementary reaction scheme were used for the calculations. This paper consists of three main topics. First, the heat release mechanisms of the HCCI engine were investigated. The results show that heat release with LTR is HCHO oxidation reactions.

Homogeneous charge compression ignition (HCCI) is regarded as the next generation combustion regime in terms of high thermal efficiency and low emissions. It is difficult to control autoignition and combustion because they are controlled primarily by the chemical kinetics of air/fuel mixture. In this study, it was investigated the characteristics of autoignition and combustion of natural gas in a four-stroke HCCI engine using experiment and elementary reactions calculation. The influence of equivalence ratio, intake temperature, intake pressure and engine speed on autoignition timing, autoignition temperature, combustion duration and the emissions of THC, CO, CO2 were investigated. And also, to clarify the influence of n-butane on autoignition and combustion of natural gas, it was changed the blend ratio of n-butane from 0 mol% to 10 mol% in methane / n-butane / air mixtures.

Homogeneous Charge Compression Ignition (HCCI) is good method to be higher efficiency and to reduce NOx emission and particular matter together than conventional SI combustion engine. But HCCI depends on chemical reaction of fuel and air mixture. So controlling of ignition timing is difficult, and HCCI is high THC and CO emissions because temperature can't reach the enough temperature to reduce those. In this study, we investigated factor for auto ignition timing and combustion completion on n-Butane/Air mixture by a two-stroke HCCI engine. Auto Ignition temperature are known to be decided by fuel(1), for n-Butane, the temperature was 1150±30K. And as we researched combustion completion from In-cylinder gas temperature, increasing In-cylinder gas temperature caused high combustion efficiency and low THC, CO emissions.

In this study, the effects of fuel properties, aromatics content and 90% distillation temperature T90, on flame temperature and soot formation were studied using a rapid compression machine (RCM). Aromatics content and T90 distillation temperature were parameters isolated from influence of each other, and from cetane number. A fuel spray was injected in the RCM combustion chamber by a single nozzle hole. The ignition and combustion processes of diesel spray were observed by a high-speed direct photography. Flame temperature and KL factor (which indicates the soot concentration), were analyzed by the two-color method. The rate of heat release was analyzed from indicated diagrams. The fuels with aromatics content showed higher flame temperature. The fuel with highest T90 distillation temperature showed highest flame temperature.

In this study, effects of nozzle hole diameter and EGR ratio on flame temperature (indication of NO formation) and KL value (indication of soot formation) were investigated. Combustion of a single diesel fuel spray in the cylinder of a rapid compression machine (RCM) was analyzed. Three nozzles with different hole diameter were used corresponding to present, near term and long term heavy duty diesel engine specifications. EGR was simulated through 2%vol. CO2 addition to the inlet air and by increase of in-cylinder surrounding gas temperature. Various types of fuels were used in this. The ignition and combustion processes of diesel fuel spray were observed by a high-speed direct photography and by indicated pressure diagrams. Flame temperature and KL factor were analyzed by a two-color method. With larger nozzle hole diameters there are larger high temperature areas. With smaller nozzle hole diameters there is more soot formed. Introduction of 2% vol.

Accurate measurements of combustion gas temperature and the coefficient of heat transfer between the gas and the combustion chamber wall of internal combustion engine in cyclic operations are difficult at present. Hence the only method available for determination of states of thermal load and heat loss to the combustion chamber wall in a cycle is to measure the instantaneous temperature on the combustion chamber wall surface accurately and precisely using proper thin-film thermocouples, then to calculate the instantanenous heat flux flowing into the wall surface by means of numerical analysis. However, it is necessary to pay adequate attention to the effects of thermophysical properties of the thermocouple materials on the measured values, since any thermocouple consists of several kinds of materials which are different from those of portions to be measured.

HCCI (Homogeneous Charge Compression Ignition) engine is expected to a new engine to be high efficiency and low emission. But it is difficult to control ignition timing and combustion duration, because ignition and combustion mainly depend on oxidation process of fuel. In this study, the focus is to clear the combustion mechanism of auto-ignition engine. By calculating chemical kinetics of elementary reactions, effects of compression speed, equivalence ratio, initial temperature and compression ratio on auto-ignition were investigated. And also, behaviors of chemical species under auto-ignition process were cleared.

Auto-ignition, which is observed in homogeneous and premixed charge compression ignition engines, allows expansion of the lean flammability limit of engine operation and realization of stable ignition and combustion over a range of ultra-lean conditions, where NOx emissions are very low. In this study, the basic combustion mechanism of auto-ignition and combustion was studied with initial mixture temperatures and compression speeds for n-butane and dimethyl ether. A single-mode type heat release process was observed with n-butane in the homogeneous charge compression ignition test engine.

ATAC (Active Thermo-Atmosphere Combustion) is autoignition combustion in two stroke engines, which occurs by diluting trapped Fuel-Air mixture with residual gas to maintain a high temperature at low load operation. In this study, two-stroke ATAC engine testing was carried out to obtain fundamental knowledge for controlling the autoignition and combustion characteristics in this premixed charge compression-ignition combustion engine. The influences of delivery ratio, equivalence ratio and enginespeed (i.e. compression speed) on autoignition timing, autoignition temperature and combustion duration were investigated. It was found that the ATAC autoignition temperature and combustion duration did not depend on the delivery ratio and equivalence ratio, but were determined by the individual fuel characteristics. Increasing the compression speed reduced the ATAC autoignition temperature a little.

Homogeneous charge compression ignition (HCCI) combustion requires high EGR rate and high intake temperature. HCCI combustion has not yet been made to operate at conditions other than low speed and low load in a four-stroke engine. Two stroke engine, however, have produced reasonable power in the HCCI combustion or active thermo-atmosphere combustion (ATAC) mode. In this paper, the nature of ATAC is discussed by spectroscopic observation to determine why the ATAC (under favorable condition) produces very low cyclic irregularity and low NO emission. ATAC low heat rejection engine and ATAC with alternative fuels are discussed.

ATAC is “bulk-like” and/or “non-propagating” combustion caused by compression autoignition of premixture, and it is stable even in the lean region. And ATAC engine is expected to be an engine using alternative fuels which are difficult to apply to usual engines because of their low cetane number. In this study, a two-stroke ATAC engine test was carried out to evaluate an adaptability of alternative fuels for lean burn. Methanol, ethanol, DME, methane and propane were used as the test fuels, and the influence of fuel characteristics on autoignition timing, combustion duration and autoignition temperature were investigated in the lean region. Using oxygenated fuels, the lean limit of ATAC operation region shifts to lean side. ATAC autoignition temperature is not depend on equivalence ratio, delivery ratio and engine speed, and it is only decided by the kind of fuel. The order of the ATAC autoignition temperature is methanol, ethanol, DME, gasoline from lower side.

High pressure fuel injection and a micro-hole nozzle were used with a rapid compression machine to study soot and nitrogen oxide reduction by creating a uniform and lean fuel distribution in the combustion chamber. The rapid compression machine was optically accessible, which allowed high-speed photography and subsequent two-color flame temperature and soot concentration measurements to be made. In addition, band spectrum radical luminescence images were also observed.

To analyze the combustion mechanism of the so-called Active Thermo-Atmosphere Combustion (ATAC) in a two-stroke S.I. engine, a measuring system to obtain images of radical luminescence in the combustion chamber was developed. The ATAC engine tested was equipped with a quartz windows as the cylinder head. The instantaneous luminescence from radical species was observed using an image intensifier with a single band pass filter for both conventional and ATAC operating conditions. At ATAC operation, emissions from OH radicals were observed before heat release began, and after that, emissions from CH were observed. It was found that the ignition was initiated over the entire area of the combustion chamber and “bulk-like” and/or “non propagating” combustion occurred during ATAC engine operation.

A single action rapid compression machine was developed to observe the soot formation and oxidation processes in a diesel spray flame. Two color method was applied to analyze the flame temperature and KL factor from the flame image taken by high speed camera. Variation in gas oxygen concentration of the surrounding gas was achieved by adding different quantities of pure oxygen, nitrogen, carbon dioxide and argon gases to charged air within a range from 17 to 25 vol.% oxygen to examine the effects of the surrounding gas composition and the temperature, and of the flame temperature on soot formation and extinction. The initial gas temperature has much effect not only on the ignition but on soot formation speed. The higher oxygen concentration gives the higher flame temperature and the faster soot oxidation rate in the flame. Carbon dioxide has a soot reduction effect in spite of its lower flame temperature.